Me CAAC=N − : A Cyclic (Alkyl)(Amino)Carbene Imino Ligand

Ligand Effects on the Formation of Imino Complexes

NHz (PPN), PhzPCHzCH(CH3)NHz (PN-21, and HzN(CHZ)~PP~Z (PN-3) resulted in the formation of [C~F~(P,PJV-PZN)II (lo), [CpFe(P,PJV-PNP)II (1 11, [CpFe(P,PJV-PPN)II (121, [CpFe(CO)(P,N-PN-2)]1 (13), and [CpFe(CO)(PJV-PN-3)11 (141, respectively. Complexes 10 and 12 were easily converted into their corresponding imino complexes [CpFe(P,P,N[CH~C(CHZPP~Z)Z(CH=NHH)~)~I (15) and [C~F~(P,PJV-[P~ZPCHZCH(PP...

Cyclic (amino)(imino)carbene complexes by borylene transfer to isocyanides.

Here we report the facile formation of boron-containing cyclic (amino)(imino)carbene complexes by reaction of a chromium borylene complex [(OC)(5)Cr=B=N(SiMe(3))(2)] with isocyanides.

Azetidine-2-carboxylic acid: a new cyclic imino acid occurring in plants.

Cyclometalation and coupling of a rigid 4,5-bis(imino)acridanide pincer ligand on yttrium.

An extremely rigid NNN-donor proligand, 4,5-bis{(diphenylmethylene)amino}-2,7,9,9-tetramethylacridan, H[AIm2] was prepared in five steps starting from 5-methyl-2-aminobenzoic acid and 4-bromotoluene. Reaction of intensely orange H[AIm2] with LiCH2SiMe3 formed deep blue Li(x)[AIm2]x (x = 2 in the solid state), while reaction with [Y(CH2SiMe3)3(THF)2] (0.5 equiv.) afforded deep blue [Y(AIm2)(AIm)...

"See me, feel me, touch me, heal me".

Community-based wind energy projects, with their small-scale, yet sizeable presence, provide a valuable opportunity to understand how individuals make sense of changes to their communities and to the surrounding landscape. Here, we examine the results of a 2013 mail survey of individuals residing in the vicinity of a 2 MW wind turbine that is located on the edge of the historic coastal town of ...